Helium (Greek helios, "sun"), symbol
He, inert, colorless, odorless gaseous element. In group 18 (or
VIIIa) of the periodic table , helium is one of the noble gases.
The atomic number of helium is 2.
The French astronomer Pierre Janssen discovered
helium in the spectrum of the corona of the sun during an eclipse
in 1868. Shortly afterward it was identified as an element and
named by the British chemist Sir Edward Frankland and the British
astronomer Sir Joseph Norman Lockyer. The gas was first isolated
from terrestrial sources in 1895 by the British chemist Sir William
Ramsay, who discovered it in cleveite, a uranium-bearing mineral.
In 1907 the British physicist Sir Ernest Rutherford showed that
alpha particles are the nuclei of helium atoms, which later investigation
confirmed.
Properties and Occurrence
Helium has monatomic molecules, and is the lightest of all gases
except hydrogen. Helium solidifies at -272.2° C (-457.9°
F) at pressures above 19,000 torr (25 atmospheres); helium boils
at -268.9° C (-452.0° F) and has a density of 0.1664 g/liter
at 20° C (68° F). The atomic weight of helium is 4.003.
Helium, like the other noble gases, is chemically
inert. Its single electron shell is filled, making possible reactions
with other elements extremely difficult and the resulting compounds
quite unstable. Molecules of compounds with neon, another noble
gas, and with hydrogen have been detected, however, and other
compounds have been suggested. Because of helium's abundance in
the universe, the existence of such reactions, however rare, could
be of importance in cosmology.
Helium is the most difficult of all gases
to liquefy and is impossible to solidify at normal atmospheric
pressures. These properties make liquid helium extremely useful
as a refrigerant and for experimental work in producing and measuring
temperatures close to absolute zero. Liquid helium can be cooled
almost to absolute zero at normal pressure by rapid removal of
the vapor above the liquid. At a temperature slightly above absolute
zero, it is transformed into helium II, also called superfluid
helium, a liquid with unique physical properties. It has no freezing
point, and its viscosity is apparently zero; it passes readily
through minute cracks and pores and will even creep up the sides
and over the lip of a container. Helium-3, the lighter helium
isotope of mass 3, which has an even lower boiling point than
ordinary helium, exhibits markedly different properties when liquefied.
Helium is the second most abundant element
in the universe, after hydrogen. At sea level, helium occurs in
the atmosphere in the proportion of 5.4 parts per million. The
proportion increases slightly at higher altitudes. About 1 part
per million of atmospheric helium consists of helium-3, now thought
to be a product of the decay of tritium, a radioactive hydrogen
isotope of mass 3. The common helium isotope, helium-4, probably
comes from radioactive alpha emitters in rocks. Natural gas, which
contains an average of 0.4 percent helium, is the major commercial
source of helium. By far the largest users of helium are agencies
of the United States government.
Uses
Because it is noncombustible, helium is preferred to hydrogen
as the lifting gas in lighter-than-air balloons; it has 92 percent
of the lifting power of hydrogen, although it weighs twice as
much. Helium is used to pressurize and stiffen the structure of
rockets before takeoff and to pressurize the tanks of liquid hydrogen
or other fuel in order to force fuel into the rocket engines.
It is useful for this application because it remains a gas even
at the low temperature of liquid hydrogen. A potential use of
helium is as a heat-transfer medium in nuclear reactors because
it remains chemically inert and non-radioactive under the conditions
that exist within the reactors.
Helium is used in inert-gas arc welding for
light metals such as aluminum and magnesium alloys that might
otherwise oxidize; the helium protects heated parts from attack
by air. Helium is used in place of nitrogen as part of the synthetic
atmosphere breathed by deep-sea divers, caisson workers, and others,
because it reduces susceptibility to the bends. This synthetic
atmosphere is also used in medicine to relieve sufferers of respiratory
difficulties because helium moves more easily than nitrogen through
constricted respiratory passages. In surgery, beams of ionized
helium from synchrocyclotron sources are proving useful in treating
eye tumors, by stabilizing or even shrinking the tumors. Such
beams are also used to shrink blood-vessel malformations in the
brains of patients.
Helium is transported as a gas in small quantities,
compressed in heavy steel cylinders. Larger amounts of helium
can be shipped as a liquid in insulated containers, thus saving
shipping costs.
Helium, which may be essential to future advanced
technologies, was not stockpiled by the U.S. government between
1973 and 1980, nor were private natural-gas producers required
to recover helium from their wells. It is estimated that some
370 million cu m (about 13 billion cu ft) of helium were lost
each year during that time. At the urging of U.S. scientists,
however, the federal government reestablished in 1980 both a national
helium reserve and the regulation of private producers.
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